Adhesion of PBO Fiber in Epoxy Composites

The high mechanical and thermal performance of poly p-phenylene- 2, 6-benzobisoxazole ( PBO ) fiber provides great potential applications as reinforcement fibers for composites. A composite of PBO fiber and epoxy resin has excellent electrical insulation properties, therefore, it is considered to be the best choice for the reinforcement in high magnetic field coils for pulsed magnetic fields up to 100 T.However, poor adhesion between PBO fiber and matrix is found because of the chemically inactive and/or relatively smooth surface of the reinforcement fiber preventing efficient chemical bonding in the interface, which is a challenging issue to improve mechanical properties. Here, we report the surface modification of PBO fibers by ultraviolet (UV)irradiation, O2 and NH3 plasma, as well as acidic treatments. The interfacial adhesion strength values of all the treatments show the similar level as determined for aramid fibers by pull-out tests, a significant impact on fibermatrix-adhesion was not achieved. The surface free energy and roughness are increased for both sized and extracted fibers after plasma treatments together with maleic anhydride grafting. The sized fiber shows marginal improvement in adhesion strength and no change in fiber tensile strength because of the barrier effect of the finish.For the extracted fiber, different surface treatments either show no apparent effect or cause reduction in adhesion strength. Atomic force microscopy (AFM) topography analysis of the fracture surfaces proved adhesive failure at the fiber surface. The fiber surface roughness is increased and more surface flaws are induced, which could result in coarse interface structures when the treated fiber surface has no adequate wetting and functional groups. The adhesion failure is further confirmed by similar adhesion strength and compression shear strength values when the fiber was embedded in various epoxy resins with different temperature behavior. The tensile strength of fiber is sensitive to surface treatment conditions as revealed by a bimodal Weibull statistical distribution analysis. Considerable strength reduction occurred, particularly for cases of acidic and plasma treatments, while UV irradiation shows the better ability to retain fiber strength.     

Transition from Multiple Macro-Cracking to Multiple Micro-Cracking in Cementitious Composites

This paper presents an experimental study of the possibility of transition from multiple macro-cracking to multiple micro-cracking in cementitious composites.Conventional polyvinyl alcohol fiber reinforced cementitious composites normally exhibit macroscopic strain-hardening and multiple cracking after the first cracks appear.However,the individual crack width at the saturated stage is normally 60 to 80 μm.In the current study,the effect of fine aggregate size on the cracking performance,especially the individual crack width in the strain-hardening stage was studied by bending tests.The results show that the individual crack widths can be reduced from 60-80 μm to 10-30 μm by modifying the particle size of the fine aggregates used in the composites.     

冷轧钢基复合材料轧制力能参数研究

在实验的基础上,提出冷轧钢基复合材料的轧制力计算模型,并由此推导冷轧钢基复合材料的轧制力计算公式.采用该公式计算出的轧制力与实验值基本符合.     

PZT／环氧树脂0—3型压电复合材料性能的研究

制备了以环氧树脂为基体，不同ＰＺＴ材料为压电相的两种０－３型压电复合材料。研究了极化工艺参数和陶瓷粉末对压电系数ｄ－３３的影响，结果表明，复合材料的压电系数ｄ－３３先随极化合场Ｅ和极化时间ｔ的增加而增加，之后趋于恒定。ＰＺＴ体积含量增加，介电常数ε２减小，则复合材料压电系数ｄ－３３增加。     

A STRUCTURAL ANALYSIS OF THREE-DIMENSIONAL BRAIDS

This paper describes a study of three-dimensional braids produced by a four-step 1 × 1 method. An analytical approach is employed in conjunction with experimental investigations to establish the relationship between the braid structure and braiding parameters. Based on microscopic observations, we divide a three-dimensional braid structure into three representative regions, i.e., the interior, surface and corner, and treat the three regions, respectively. Three types of microstructural unit-cell models are then established. The surface characteristics and the relationship between the interior and surface unit-cells have been derived. Good agreement has been obtained between the calculated and measured values of fiber volume fraction of the braided composite samples.     

少齿差金属橡胶复合摆线齿轮副动态特性分析

金属橡胶具有很强的变形补偿能力,可帮助实现高精密传动。介绍了复合摆线齿轮副的结构及原理,建立了齿轮副的三维模型,并在ADAMS中建立起此金属橡胶齿轮副的刚柔混合模型后进行动力学仿真,分析了弹性模量变化、双联齿轮间隙及两对齿轮副中心距对少齿差复合摆线齿轮副角速度、角加速度、啮合力和传动误差的影响,同时对比分析了刚性、刚柔复合2种齿轮副输出轮角速度以及传动误差的差异。结果表明增大少齿差齿轮副中心距、适当增大金属橡胶弹性模量和双联齿轮间隙可减小振动波动,刚柔复合摆线齿轮的角速度和传动误差整体波动均比刚性齿轮副小,说明金属橡胶在新型NN型两级少齿差齿轮副中起到了减振效果。     

SiCf/Ti2AlNb复合材料的界面反应及热稳定性

界面反应层是影响SiC纤维(SiC_f)增强钛基复合材料力学性能的重要因素,本文研究了SiC_f/Ti₂AlNb复合材料在热等静压成型以及热暴露过程中的界面反应、界面元素分布规律和界面热稳定性.研究结果表明:SiC_f/Ti₂AlNb复合材料内部元素扩散形成的界面产物主要为TiC,在热暴露过程中出现了TiSi₂和NbSi₂相.SiC_f/Ti₂AlNb复合材料界面反应层的厚度长大符合Arrhenius定律,其界面反应层厚度长大速率随着热暴露温度的升高而增加.界面反应层长大激活能为24.27kJ/mol,界面层长大频率因子为2.80×10^-4 m/s^1/2.SiC_f/Ti₂AlNb复合材料界面在700℃及以下温度具备良好的热稳定性.     

工程水泥基复合材料高温损伤超声特性

为了研究工程水泥基复合材料(ECC)在高温作用后的损伤机理及超声特性,对不同温度(20,105,250,400,600和800℃)作用后的ECC试件进行超声波和抗压强度测试.结果表明:超声波通过高温作用后ECC的波形幅值、主频幅值、能量和ECC抗压强度的变化趋势相同;不同温度作用后40~50kHz频段的能量占比均最大,约为0~300kHz总能量的15%;在20~250℃作用后声速变化不大,温度高于400℃后声速随温度升高而降低.原因是高温后自由水汽化、水化产物分解和骨料物性改变,导致孔隙蒸汽压力升高和骨料界面损伤,ECC内部裂纹产生并扩展.扫描电镜测试结果表明,PVA纤维随温度升高发生软化、熔化和汽化,ECC基体中产生空隙和孔道并与裂纹连通形成网络,有利于释放孔隙蒸汽压力,减弱ECC高温损伤.研究表明超声特性可以有效反映ECC的高温损伤演化过程.     

基于矩阵分析的橡胶透水混凝土正交试验

选取水胶比、橡胶粒径、橡胶掺量、VAE-707乳液掺量及目标孔隙率五个因素对橡胶透水混凝土进行正交试验设计,研究其对抗压、抗折强度及透水性能的影响。利用矩阵分析法和灰色决策进行分析,得到橡胶透水混凝土最优配合比:水胶比0.3、橡胶颗粒大小0.425 mm、橡胶颗粒掺量3%、VAE-707乳液掺量为6%、目标孔隙率为16%;其中目标孔隙率对透水混凝土的性能贡献率最大,透水混凝土的抗压、抗折强度随着目标孔隙率的升高而降低,而透水系数则呈相反规律;透水混凝土实测孔隙率整体小于设计孔隙率,有效孔隙率约占总孔隙率的80%～90%,封闭孔占总孔隙10%～20%左右。